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Hint: Resonance is the way of describing the delocalization of bonded electrons or non-bonding electrons in a conjugated system. The intermediate structures formed are called resonating structure. The structure that collectively represents all resonating structures is believed to be most stable and is called the resonating hybrid.
Complete answer:
Carboxylic acid is more acidic than phenol. This can be explained on the basis of resonance, phenoxide ion has more number of resonating structures as compared to carboxylate ion.
In resonating structures of phenoxide ion, the negative charge is present on one electronegative oxygen atom and the less electronegative carbon atom. The contribution of resonance structures towards resonance stabilization of phenoxide ion is less.
In resonating structures of carboxylate ions, the negative charge is present on two electronegative oxygen atoms. The contribution of resonance structures towards resonance stabilization of carboxylate ion is more.
Hence carboxylate ions are more resonance stabilized than the phenoxide ions. Due to this the carboxylic acid is more acidic than phenol (higher the stability leads to greater acidic strength).
Note:Acidic strength of phenol and carboxylic acid depend upon stability of resonating structures. Carboxylate ions exhibit higher stability in comparison to phenoxide ions, thus higher stability leads to greater acidic strength.
Complete answer:
Carboxylic acid is more acidic than phenol. This can be explained on the basis of resonance, phenoxide ion has more number of resonating structures as compared to carboxylate ion.
In resonating structures of phenoxide ion, the negative charge is present on one electronegative oxygen atom and the less electronegative carbon atom. The contribution of resonance structures towards resonance stabilization of phenoxide ion is less.
In resonating structures of carboxylate ions, the negative charge is present on two electronegative oxygen atoms. The contribution of resonance structures towards resonance stabilization of carboxylate ion is more.
Hence carboxylate ions are more resonance stabilized than the phenoxide ions. Due to this the carboxylic acid is more acidic than phenol (higher the stability leads to greater acidic strength).
Note:Acidic strength of phenol and carboxylic acid depend upon stability of resonating structures. Carboxylate ions exhibit higher stability in comparison to phenoxide ions, thus higher stability leads to greater acidic strength.
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