
Write the preparation of benzoic acid from the following:
(a) Styrene
(b) Benzamide
(c) Dry ice
Answer
447.9k+ views
Hint: To solve this question, we first need to know what benzoic acid, styrene, benzamide, and dry ice.
Benzoic acid: A colorless and crystalline derivative of benzene having formula
Styrene: A colorless and oily derivative of benzene having formula .
Benzamide: A white and solid derivative of benzoic acid having formula .
Dry ice: A cooling agent which is the solid form of the gas carbon dioxide .
Complete answer:
Let us look at the reactions involving the preparation of benzoic acid from styrene, benzamide, and dry ice.
a) Using styrene (phenylethane) to prepare benzoic acid.
While converting styrene to benzoic acid, an oxidizing agent is used.
Either potassium permanganate or potassium dichromate, in the presence of sulfuric acid, acts as a strong oxidizing agent and converts styrene to benzoic acid.
Styrene is first converted to potassium benzoate and then acidified to give benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, carbon dioxide gas is released and a water molecule is produced as by-products.
b) Using benzamide to prepare benzoic acid.
In the presence of an acid like dilute hydrochloric acid, the hydrolysis of benzamide with sodium hydroxide (NaOH) forms benzoic acid.
Benzamide is first converted to sodium benzoate which is further acidified to benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, ammonia is released as the by-product.
c) Using dry ice to prepare benzoic acid.
When dry ice or solid carbon dioxide is added to a solution of phenyl magnesium iodide in dry ether, an adduct is formed. The adduct formed is a magnesium salt of carboxylic acid.
When this adduct is hydrolyzed in the presence of an acid, it gives benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, magnesium hydroxide (MgOH) is formed as a by-product.
Note:
It should be noted that the gas released from dry ice can increase the levels of carbon dioxide in the blood and can cause hypercapnia.
Also, styrene is considered to be carcinogenic and toxic, especially when in contact with skin or eyes.
Benzoic acid on the other hand is produced naturally in many plants and animal species.
Benzoic acid: A colorless and crystalline derivative of benzene having formula
Styrene: A colorless and oily derivative of benzene having formula
Benzamide: A white and solid derivative of benzoic acid having formula
Dry ice: A cooling agent which is the solid form of the gas carbon dioxide
Complete answer:
Let us look at the reactions involving the preparation of benzoic acid from styrene, benzamide, and dry ice.
a) Using styrene (phenylethane) to prepare benzoic acid.
While converting styrene to benzoic acid, an oxidizing agent is used.
Either potassium permanganate or potassium dichromate, in the presence of sulfuric acid, acts as a strong oxidizing agent and converts styrene to benzoic acid.
Styrene is first converted to potassium benzoate and then acidified to give benzoic acid.
The reaction proceeds as follows:

Along with benzoic acid, carbon dioxide
b) Using benzamide to prepare benzoic acid.
In the presence of an acid like dilute hydrochloric acid, the hydrolysis of benzamide with sodium hydroxide (NaOH) forms benzoic acid.
Benzamide is first converted to sodium benzoate which is further acidified to benzoic acid.
The reaction proceeds as follows:

Along with benzoic acid, ammonia
c) Using dry ice to prepare benzoic acid.
When dry ice or solid carbon dioxide
When this adduct is hydrolyzed in the presence of an acid, it gives benzoic acid.
The reaction proceeds as follows:

Along with benzoic acid, magnesium hydroxide (MgOH) is formed as a by-product.
Note:
It should be noted that the gas released from dry ice can increase the levels of carbon dioxide
Also, styrene is considered to be carcinogenic and toxic, especially when in contact with skin or eyes.
Benzoic acid on the other hand is produced naturally in many plants and animal species.
Recently Updated Pages
Master Class 11 Accountancy: Engaging Questions & Answers for Success

Master Class 11 Social Science: Engaging Questions & Answers for Success

Master Class 11 Economics: Engaging Questions & Answers for Success

Master Class 11 Physics: Engaging Questions & Answers for Success

Master Class 11 Biology: Engaging Questions & Answers for Success

Class 11 Question and Answer - Your Ultimate Solutions Guide

Trending doubts
Explain why it is said like that Mock drill is use class 11 social science CBSE

The non protein part of an enzyme is a A Prosthetic class 11 biology CBSE

Which of the following blood vessels in the circulatory class 11 biology CBSE

What is a zygomorphic flower Give example class 11 biology CBSE

1 ton equals to A 100 kg B 1000 kg C 10 kg D 10000 class 11 physics CBSE

The deoxygenated blood from the hind limbs of the frog class 11 biology CBSE
