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Write the equations for reaction of chlorine with the following:
(a) Cold and dilute NaOH
(b) Excess NH3
(c) Ca(OH)2
(d) Na2S2O3

Answer
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Hint: We know that chlorine has an atomic number of seventeen. Chlorine is an extremely reactive gas and it is an oxidising agent. It has the highest electron affinity. It is the third highest electronegative element in the modern periodic table after fluorine and oxygen. Chlorine is a P Block element.

Complete step by step solution:
As in the question we are given to react chlorine with four other different reactants. We will try to solve one by one. So,

(a) When we react chlorine with Cold and dilute NaOH, the chemical equation we will get is 2NaOH(aq)+Cl2(g)NaCl(aq)+NaOCl(aq)+H2O. Here we can see that we will get sodium chloride, water and sodium chlorate as products of the reaction.

(b) When we react chlorine with Excess NH3, the chemical equation we will get is 8NH3+Cl26NH4Cl+N2. Here we can see that we will get nitrogen gas and ammonium chloride as products of the reaction.

(c) When we react chlorine with Ca(OH)2, the chemical equation we will get is Ca(OH)2+Cl2CaOCl2+H2O. Here we can see that we will get Calcium Hypochlorite and water as products of the reaction.

(d) When we react chlorine and Na2S2O3, the chemical equation we will get is Na2S2O3+Cl2+H2ONa2SO4+2HCl+S. Here we can see that we will get hydrochloric acid,sodium sulphate and sulphur as products of the reaction.

Note: Always remember that chlorine is a very reactive element. It has high electronegativity. It is a yellow green gas. It is a halogen. Remember the following reactions of chlorine because these are very important. 2NaOH(aq)+Cl2(g)NaCl(aq)+NaOCl(aq)+H2O, 8NH3+Cl26NH4Cl+N2,Ca(OH)2+Cl2CaOCl2+H2O,Na2S2O3+Cl2+H2ONa2SO4+2HCl+S.
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