
Which of the following reactions is non-stereospecific but stereoselective?
\[A)S{N_1} \\
B){E_1} \\
C){E_2} \\
D){E_1}cB \]
Answer
512.7k+ views
Hint : A stereospecific mechanism specifies the stereochemical outcome of a given reactant, whereas a stereoselective reaction selects products from those made available by the same, non-specific mechanism acting on a given reactant of stereoisomeric reactants, each behaves in its own specific way.
Complete Step By Step Answer:
The main difference between stereospecific and stereoselective reactions is that a stereospecific reaction gives one specific product whereas stereoselective reaction gives multiple products.
A $ {E_1} $ reaction involves the deprotonation of a hydrogen nearby the carbocation resulting in the formation of an alkene product. In order to accomplish this, a Lewis base is required. It is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism
The one-step mechanism is known as the $ {E_2} $ reaction, and the two-step mechanism is known as the $ {E_1} $ reaction. The numbers refer not to the number of steps in the mechanism, but rather to the kinetics of the reaction. $ {E_2} $ Is bimolecular while $ {E_1} $ is unimolecular. Elimination may be considered the reverse of an additional reaction.
It is a two-step process of elimination: ionization and deprotonation. Ionization the carbon-halogen bond breaks to give a carbocation intermediate. Deprotonation of the carbocation.
So, the correct answer is $ B){E_1} $ .
Note :
There are competitions between $ {E_2} $ and $ {S_N}2 $ and also between $ {E_1} $ and $ {S_N}1 $ . Substitution generally predominates and elimination occurs only during precise circumstances. Generally, elimination is favored over substitution when steric hindrance around the $ \alpha - $ carbon increases, a stronger base is used, temperature increases and when the base is a poor nucleophile. Bases with steric bulk are often poor nucleophiles.
Complete Step By Step Answer:
The main difference between stereospecific and stereoselective reactions is that a stereospecific reaction gives one specific product whereas stereoselective reaction gives multiple products.
A $ {E_1} $ reaction involves the deprotonation of a hydrogen nearby the carbocation resulting in the formation of an alkene product. In order to accomplish this, a Lewis base is required. It is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism
The one-step mechanism is known as the $ {E_2} $ reaction, and the two-step mechanism is known as the $ {E_1} $ reaction. The numbers refer not to the number of steps in the mechanism, but rather to the kinetics of the reaction. $ {E_2} $ Is bimolecular while $ {E_1} $ is unimolecular. Elimination may be considered the reverse of an additional reaction.
It is a two-step process of elimination: ionization and deprotonation. Ionization the carbon-halogen bond breaks to give a carbocation intermediate. Deprotonation of the carbocation.
So, the correct answer is $ B){E_1} $ .
Note :
There are competitions between $ {E_2} $ and $ {S_N}2 $ and also between $ {E_1} $ and $ {S_N}1 $ . Substitution generally predominates and elimination occurs only during precise circumstances. Generally, elimination is favored over substitution when steric hindrance around the $ \alpha - $ carbon increases, a stronger base is used, temperature increases and when the base is a poor nucleophile. Bases with steric bulk are often poor nucleophiles.
Recently Updated Pages
Master Class 11 Computer Science: Engaging Questions & Answers for Success

Master Class 11 Business Studies: Engaging Questions & Answers for Success

Master Class 11 Economics: Engaging Questions & Answers for Success

Master Class 11 English: Engaging Questions & Answers for Success

Master Class 11 Maths: Engaging Questions & Answers for Success

Master Class 11 Biology: Engaging Questions & Answers for Success

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

There are 720 permutations of the digits 1 2 3 4 5 class 11 maths CBSE

Discuss the various forms of bacteria class 11 biology CBSE

Draw a diagram of a plant cell and label at least eight class 11 biology CBSE

State the laws of reflection of light

Explain zero factorial class 11 maths CBSE

