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Hint: As we know that the Sandmeyer’s reaction is a chemical reaction in organic chemistry which is used in the synthesis of aryl halides from aryl diazonium salts by using copper salts as reagents or catalysts. This reaction is an example of radical-nucleophilic aromatic substitution. So here we have to tell which compound cannot be prepared by Sandmeyer's reaction.
Complete answer:
Let us first discuss about Sandmeyer's reaction as follows:-
-Sandmeyer's reaction: It is a chemical reaction in organic chemistry which is used in the synthesis of aryl halides from aryl diazonium salts by using copper salts as reagents or catalysts. This reaction is useful as an amino group on an aromatic ring can be substituted with different groups. During this reaction, the amino group which is attached to an aromatic ring is converted into diazonium salt that is ultimately transformed into various functional groups as desired.
-The reaction takes place as follows:-
As we can see, sodium nitrate is used with hydrochloric acid to convert amino groups on benzene rings to diazonium salt. Now we can bring any substituent at that place using various reagents. When copper salts of halide are used as reagent in the reaction, then it is referred to as Sandmeyer's reaction.
-Generally copper salt of chlorine and bromine are available and hence used for the production of chlorobenzene and bromobenzene whereas iodobenzene is produced using potassium iodide (KI) instead of copper salt and therefore it cannot be produced through Sandmeyer's reaction.
-For the formation of fluorobenzene, diazonium salt is made to react with fluoroboric acid ($HB{{F}_{4}}$) and is heated at high temperature. This reaction is known as the Balz Schiemann reaction.
From the above data we can conclude that (C) Iodobenzene and (D) Fluorobenzene cannot be prepared by Sandmeyer's reaction.
Note:
-Remember that $NaN{{O}_{2}}$ reacts with HCl to form $HN{{O}_{2}}$ which acts as a intermediate in the formation of diazonium salt and this reaction takes place at 0 to 5$^{\circ }C$ temperature.
-Sandmeyer's reaction is also used to produce benzonitriles through the process of cyanation.
Complete answer:
Let us first discuss about Sandmeyer's reaction as follows:-
-Sandmeyer's reaction: It is a chemical reaction in organic chemistry which is used in the synthesis of aryl halides from aryl diazonium salts by using copper salts as reagents or catalysts. This reaction is useful as an amino group on an aromatic ring can be substituted with different groups. During this reaction, the amino group which is attached to an aromatic ring is converted into diazonium salt that is ultimately transformed into various functional groups as desired.
-The reaction takes place as follows:-
As we can see, sodium nitrate is used with hydrochloric acid to convert amino groups on benzene rings to diazonium salt. Now we can bring any substituent at that place using various reagents. When copper salts of halide are used as reagent in the reaction, then it is referred to as Sandmeyer's reaction.
-Generally copper salt of chlorine and bromine are available and hence used for the production of chlorobenzene and bromobenzene whereas iodobenzene is produced using potassium iodide (KI) instead of copper salt and therefore it cannot be produced through Sandmeyer's reaction.
-For the formation of fluorobenzene, diazonium salt is made to react with fluoroboric acid ($HB{{F}_{4}}$) and is heated at high temperature. This reaction is known as the Balz Schiemann reaction.
From the above data we can conclude that (C) Iodobenzene and (D) Fluorobenzene cannot be prepared by Sandmeyer's reaction.
Note:
-Remember that $NaN{{O}_{2}}$ reacts with HCl to form $HN{{O}_{2}}$ which acts as a intermediate in the formation of diazonium salt and this reaction takes place at 0 to 5$^{\circ }C$ temperature.
-Sandmeyer's reaction is also used to produce benzonitriles through the process of cyanation.
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