Question

The total number of stereoisomers of \[{\rm{2,3 - }}\] dibromobutane is ?
(A) 2
(B) 3
(C) 4
(D) 5

Answer 1

Hint: As we know that the structure of \[{\rm{2,3 - }}\] dibromobutane is shown as \[C{H_3} - CHBr - CHBr - C{H_3}\]. The non- superimposable mirror images of \[{\rm{2,3 - }}\] dibromobutane will give the stereoisomers.

Complete step by step answer:
Stereoisomerism-The isomers in which the structures of compounds are same but the spatial arrangements of substituents are different are called stereoisomers.
The stereoisomers are of two types;
Geometrical isomers - The molecules which have cis and trans geometry.
Optical isomers - If the molecule does not contain any plane of symmetry and also the molecule does not give superimposable mirror images then it is known as optical isomers.
If the bromine atom is present above the plane as shown in figure-

If the bromine atom is present below the plane as shown in figure-

Both of These are enantiomers.
If the one bromine atom is present above the plane and one below the plane as shown in figure-

It also gives a stereoisomerism of \[{\rm{2,3 - }}\] dibromobutane.
Therefore, the total number of stereoisomers of \[{\rm{2,3 - }}\]dibromobutane is three.

The correct option is (B).

Note: When the molecule contains four different groups or atoms then it is known as chiral molecule. The chiral molecule rotates the plane polarised light in either left or right direction to the direction of plane polarization then the molecule is known as optically active.
The optically active molecule gives the pair of enantiomers which are non-superimposable mirror images.