Question

The tetrahedral arrangement of perchlorate ion is due to:
(A) presence of a lone pair of electrons.
(B) trigonal bipyramidal shape of the ion.
(C) $ s{{p}^{3}} $ hybridisation.
(D) $ s{{p}^{2}} $ hybridisation.

Answer 1

Hint: We know that basically, chlorate ion has a molecular formula $ Cl{{O}^{3-}} $ . These are the salts of chloric acid. Further, the metal chlorates can be prepared by adding chlorine to metal hydroxides such as $ KOH $ . So, to solve this question we need to draw the structure and then determine its shape.

Complete answer:
Chlorates are basically the salt of chloric acid. Some of the examples of chlorates are sodium chlorate, potassium chlorate, magnesium chlorate etc. Now, only one Lewis structure cannot represent the chlorate ion since all the bonds are of the same length and the chlorine atom is further hypervalent. So, it is considered as a hybrid of multiple resonance structures. In perchlorate ion $ O-Cl-O $ bond angle $ {{109.5}^{o}}~ $ due to four groups of bonding electrons and no lone pairs of electrons.
Due to $ s{{p}^{3}} $ hybridisation of $ Cl $ atom, it has a tetrahedral structure.

Now, the chlorate ion is $ s{{p}^{3}} $ hybridized with three bond pairs and one lone pair, so its shape is pyramidal. Moreover, three oxygen atoms will have one unpaired orbital and the chlorine’s unoccupied d orbitals will be used for bonding.
Therefore, correct answer is option C.

Note:
Remember that the chlorates are powerful oxidizers and should be kept away from easily oxidized materials. Moreover, the mixtures of chlorate salts with combustible material like charcoal, organic solvents, and metals will readily deflategate. These were widely used in pyrotechnics but not their use has fallen due to their instability. Further, these are relatively toxic, though they form generally harmless chlorides on reduction.