
The standard enthalpy of formation of is 46.0 kJ/mol. If the enthalpy of formation of from its atoms is -436 kJ/mol and that of is -712 kJ/mol, the average bond enthalpy of N — H bond in is:a) -1102 kJ/molb) -964 kJ/molc) +352 kJ/mold) +1056 kJ/mol
Answer
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Hint: Bond dissociation enthalpy/energy is defined as the amount of energy required to dissociate a particular bond present in a compound. It is done via homolytic fracture which produces the radical species as a result.
Complete step by step solution:
Note: Enthalpy of formation or bond formation enthalpy is given in the question is negative but the reaction mechanism we have taken in the answer involves bond breaking. Hence, the values need to be taken as positive.
The chemical reaction for the formation of Ammonia ( ) can be given as:
We have been given in the question that the:
Standard enthalpy of formation of ( ) = 46.0 kJ/mol.
Enthalpy of formation or Bond enthalpy of from its atoms ( )= -436 kJ/mol
Enthalpy of formation or Bond enthalpy of from its atoms ( ) = -712 kJ/mol
We know that,
Putting the values in above equation, we get,
After rearranging,
Therefore, the average bond enthalpy of N-H bond in NH is .
So, the correct option is (c).
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