Answer
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Hint: Because of the acidity of alpha hydrogens in carbonyl compounds, they show keto-enol tautomerism. The keto and enol forms are called Tautomers. They are rapidly interconvertible between keto and enol forms.
Complete step by step answer:
The equilibrium between tautomers ( keto and enol forms) is rapid under normal conditions and it strongly favors one of the isomers (keto form-99.99%).
For example take a simple ketone like Acetone.
Acetone shows the keto-enol tautomerism as follows.
-Due to the presence of alpha hydrogens reasonable for the formation of this type of isomerism in carbonyl compounds.
-Coming to the given options, option A, Tautomerism can be catalyzed by acid and base both. Yes it is correct by adding a small amount of acid and base we can increase the chances of showing keto-enol tautomerism. Because acid or base catalyze the tautomerism by proton transfer. We can see the mechanism of addition of acid to keto form as follows. So, option A is correct.
-Coming to option B, Tautomers are present in dynamic equilibrium state. Generally, the chemical equilibrium in keto-enol tautomerism is extremely thermodynamically driven. Generally at room temperature equilibrium heavily favors the existence of the keto form. If we increase the temperature a little bit more then keto converts into enol form. So, option B is also correct.
-Coming to option C, Generally keto form is more stable than enol form in simple ketone. Yes at room temperature the equilibrium between keto and enol form greatly favors the formation of the keto form. Because at room temperature keto form is more stable than enol form. So, option C is also correct.
Therefore all the options A, B and C are correct.
So, the correct option is D, all of the above.
Note: Tautomers of a compound which differ only in the position of the hydrogen atom. Due to the presence of alpha hydrogen the keto-enol tautomerism exists. Alpha hydrogens mean the hydrogens which are attached to the carbon that is directly attached to electron withdrawing groups like carbonyl functional groups.
Complete step by step answer:
The equilibrium between tautomers ( keto and enol forms) is rapid under normal conditions and it strongly favors one of the isomers (keto form-99.99%).
For example take a simple ketone like Acetone.
Acetone shows the keto-enol tautomerism as follows.
-Due to the presence of alpha hydrogens reasonable for the formation of this type of isomerism in carbonyl compounds.
-Coming to the given options, option A, Tautomerism can be catalyzed by acid and base both. Yes it is correct by adding a small amount of acid and base we can increase the chances of showing keto-enol tautomerism. Because acid or base catalyze the tautomerism by proton transfer. We can see the mechanism of addition of acid to keto form as follows. So, option A is correct.
-Coming to option B, Tautomers are present in dynamic equilibrium state. Generally, the chemical equilibrium in keto-enol tautomerism is extremely thermodynamically driven. Generally at room temperature equilibrium heavily favors the existence of the keto form. If we increase the temperature a little bit more then keto converts into enol form. So, option B is also correct.
-Coming to option C, Generally keto form is more stable than enol form in simple ketone. Yes at room temperature the equilibrium between keto and enol form greatly favors the formation of the keto form. Because at room temperature keto form is more stable than enol form. So, option C is also correct.
Therefore all the options A, B and C are correct.
So, the correct option is D, all of the above.
Note: Tautomers of a compound which differ only in the position of the hydrogen atom. Due to the presence of alpha hydrogen the keto-enol tautomerism exists. Alpha hydrogens mean the hydrogens which are attached to the carbon that is directly attached to electron withdrawing groups like carbonyl functional groups.
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