
Predict in which of the following entropy decreases:
A. A liquid crystallizes into a solid.
B. Temperature of a crystalline solid raised from to
C.
D.
Answer
496.5k+ views
Hint: When a small amount of heat ΔQ is added to a substance at temperature T, without changing its temperature appreciably, the entropy of the substance changes by When heat is removed, the entropy decreases, when heat is added the entropy increases. Entropy has units of Joules per Kelvin.
Complete step by step answer:
(a) Option 1st: When a liquid crystallizes into a solid, the molecule obtains an ordered state and hence, entropy decreases.
(b) Option 2nd: At , the constituent particles are static and entropy is minimum. If temperature is raised to , these begin to move and oscillate about their equilibrium positions in the lattice and the system becomes more disordered, hence entropy increases.
(c) Option 3rd:
In this reaction, the reactant, NaHCO3 is a solid and it has low entropy. Among products, there are one solid and two gases. So, the products represent a condition of higher entropy.
(d) Option 4th:
Here, one molecule of hydrogen gives two hydrogen atoms i.e. the number of particles increases leading to more disordered state. Two moles of H-atoms have higher entropy than one mole of hydrogen molecule.
So the correct option is A
Note:
A phase change from a liquid to a solid (i.e. freezing), or from a gas to a liquid (i.e. condensation) results in decrease in the disorder of the substance, and a decrease in the entropy. The entropy of a framework relies upon its inward energy and its outer boundaries, for example, its volume. In as far as possible, this reality prompts a condition relating the adjustment in the inward energy U to changes in the entropy and the outside boundaries.
Complete step by step answer:
(a) Option 1st: When a liquid crystallizes into a solid, the molecule obtains an ordered state and hence, entropy decreases.
(b) Option 2nd: At
(c) Option 3rd:
In this reaction, the reactant, NaHCO3 is a solid and it has low entropy. Among products, there are one solid and two gases. So, the products represent a condition of higher entropy.
(d) Option 4th:
Here, one molecule of hydrogen gives two hydrogen atoms i.e. the number of particles increases leading to more disordered state. Two moles of H-atoms have higher entropy than one mole of hydrogen molecule.
So the correct option is A
Note:
A phase change from a liquid to a solid (i.e. freezing), or from a gas to a liquid (i.e. condensation) results in decrease in the disorder of the substance, and a decrease in the entropy. The entropy of a framework relies upon its inward energy and its outer boundaries, for example, its volume. In as far as possible, this reality prompts a condition relating the adjustment in the inward energy U to changes in the entropy and the outside boundaries.
Latest Vedantu courses for you
Grade 10 | CBSE | SCHOOL | English
Vedantu 10 CBSE Pro Course - (2025-26)
School Full course for CBSE students
₹37,300 per year
Recently Updated Pages
Master Class 11 Economics: Engaging Questions & Answers for Success

Master Class 11 Accountancy: Engaging Questions & Answers for Success

Master Class 11 English: Engaging Questions & Answers for Success

Master Class 11 Social Science: Engaging Questions & Answers for Success

Master Class 11 Physics: Engaging Questions & Answers for Success

Master Class 11 Biology: Engaging Questions & Answers for Success

Trending doubts
How many moles and how many grams of NaCl are present class 11 chemistry CBSE

How do I get the molar mass of urea class 11 chemistry CBSE

Plants which grow in shade are called A Sciophytes class 11 biology CBSE

A renewable exhaustible natural resource is A Petroleum class 11 biology CBSE

In which of the following gametophytes is not independent class 11 biology CBSE

Find the molecular mass of Sulphuric Acid class 11 chemistry CBSE
