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$ {P_4}{O_6} $ reacts with water to give:
(A) $ {H_3}P{O_3} $
(B) $ {H_2}{P_2}{O_7} $
(C) $ HP{O_3} $
(D) $ {H_3}P{O_4} $

Answer
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Hint: Phosphorus trioxide reacts with hydrogen chloride to give phosphorous trichloride and phosphoric acid. In the given question we need to know the product formed when the $ {P_4}{O_6} $ reacts with water.

Complete step by step answer:
 $ {P_4}{O_6} $ reacts with water to give phosphoric acid.
The chemical name of $ {P_4}{O_6} $ is Phosphorus trioxide.
The structure is:
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It is formed by burning phosphorus in the limited supply of oxygen. The reaction is as follows:
 $ {P_4} + 3{O_2} \to {P_4}{O_6} $
This product reacts with water and forms phosphorus acid. The chemical formula of phosphoric acid is $ {H_3}P{O_3} $ The structure is:
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The reaction occurs as follows: $ {P_4}{O_6} + 6{H_2}O \to 4{H_3}P{O_3} $
Hence, option A. $ {H_3}P{O_3} $ is the correct answer to the given question.

Additional information:
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 $ {H_3}P{O_3} $ exists in tautomeric form because they are readily convertible and the former is called phosphonic acid whereas the latter is called phosphoric acid.

Note:
Uses of $ {H_3}P{O_3} $ :
For the production of basic lead phosphite. It is used as a stabilizer in Polyvinyl chloride and other polymers containing chlorine.
As a reducing agent: it is a strong reducing agent which is also used in production of synthetic fibers and pesticides.
As a ligand: with the metals of $ {d^6} $ configuration, it acts as a ligand by forming a co-ordinate bond with those metals.