Question

What is the major product P in the above reaction?

A)

B)

C)

D)

Answer 1

Hint: Concentrated sulphuric acid is a dehydrating agent. The dehydrating agent removes water from the compounds. The major product depends upon the stability of the formed carbocation.

Complete answer:
Concentrated sulphuric acid works as a dehydrating agent, so it discards water molecules from the compound and thus dehydrates the compound. These reactions are known as dehydration reactions and the substance which causes dehydration is known as a dehydrating agent.
The lone pair of electrons of the hydroxyl group of the reactant attacks on the sulphuric acid and gets protonated. Then the water molecule removes forming a carbocation. The carbocation is ${2^ \circ }$. Which will convert into ${3^ \circ }$ carbocation because ${3^ \circ }$ carbocation is more stable than ${2^ \circ }$ carbocation.
The conversion of ${2^ \circ }$ carbocation to ${3^ \circ }$ carbocation takes place by 1,2 - methyl shift.
The methyl shifting is shown as follows:

After the methyl shifting, proton from nearby carbon is removed to form an alkene.

Therefore, option (D) is correct.

Note: When a carbon is attached with only one other carbon, the carbon is known as ${1^ \circ }$. If the carbon is attached with two other carbons, the carbon is known as ${2^ \circ }$ carbon similarly the ${3^ \circ }$ carbon is attached with three other carbons. The order of stability of carbocation is: ${3^ \circ } > {2^ \circ } > {1^ \circ }$. As the number of methyl groups increases the $ + {\text{I}}$ effect increases, so the stability of the carbocation increases. Concentrated sulphuric acid is a strong oxidizing agent and also a dehydrating agent.