How is maleic anhydride produced?
Answer
581.4k+ views
Hint :Maleic anhydride is an organic compound. $ {C_2}{H_2}{(CO)_2}O $ is the formula for maleic anhydride. It is maleic acid's acid anhydride. It has an acrid odor and is colorless or white. It's made on a wide scale in the manufacturing sector for use in coatings and polymers.
Complete Step By Step Answer:
- The vapor-phase oxidation of n-butane produces maleic anhydride. The backbone is dehydrogenated and the methyl groups are converted to carboxylate.
- The combination of benzene and butane is pumped into a stream of hot air and moved into a high-temperature catalyst bed. To avoid the mixture from igniting, the air-to-hydrocarbon ratio is controlled. Vanadium pentoxide and molybdenum trioxide are the catalysts used for the benzene route, whereas vanadium phosphate is used for the butane route:
$ {C_4}{H_{10}} + 3.5{O_2} \to {C_4}{H_2}{O_3} + 4{H_2}O{\text{ }}\Delta H = - 1236kjmo{l^{ - 1}} $
Complete combustion of the butane, which is twice as exothermic as partial oxidation, is the main competing method. Older methods used naphthalene as a feedstock, whereas newer methods use o-xylene.
- Maleic anhydride has diverse chemistry, owing to its widespread availability and bifunctional reactivity. Maleic acid, $ Cis - HOOC - CH = CH - COOH $ , is generated when it hydrolyzes. The half-ester is formed when alcohols are used, for example, $ Cis - HOOC - CH = CH - COO{H_3} $ .
- It has various names such as
Furan-2,5-dione
cis-Butenedioic anhydride
2,5-Furanedione
Maleic acid anhydride
Toxilic anhydride
Note :
- Maleic anhydride is used as a base in Diels-Alder reactions. It was first used in 1928 for research on the reaction between maleic anhydride and 1,3-butadiene, because of this the Nobel Prize was awarded to Otto Paul Hermann Diels and Kurt Alder in 1950.
- Unsaturated polyester resins account for around half of the world's maleic anhydride production.
Complete Step By Step Answer:
- The vapor-phase oxidation of n-butane produces maleic anhydride. The backbone is dehydrogenated and the methyl groups are converted to carboxylate.
- The combination of benzene and butane is pumped into a stream of hot air and moved into a high-temperature catalyst bed. To avoid the mixture from igniting, the air-to-hydrocarbon ratio is controlled. Vanadium pentoxide and molybdenum trioxide are the catalysts used for the benzene route, whereas vanadium phosphate is used for the butane route:
$ {C_4}{H_{10}} + 3.5{O_2} \to {C_4}{H_2}{O_3} + 4{H_2}O{\text{ }}\Delta H = - 1236kjmo{l^{ - 1}} $
Complete combustion of the butane, which is twice as exothermic as partial oxidation, is the main competing method. Older methods used naphthalene as a feedstock, whereas newer methods use o-xylene.
- Maleic anhydride has diverse chemistry, owing to its widespread availability and bifunctional reactivity. Maleic acid, $ Cis - HOOC - CH = CH - COOH $ , is generated when it hydrolyzes. The half-ester is formed when alcohols are used, for example, $ Cis - HOOC - CH = CH - COO{H_3} $ .
- It has various names such as
Furan-2,5-dione
cis-Butenedioic anhydride
2,5-Furanedione
Maleic acid anhydride
Toxilic anhydride
Note :
- Maleic anhydride is used as a base in Diels-Alder reactions. It was first used in 1928 for research on the reaction between maleic anhydride and 1,3-butadiene, because of this the Nobel Prize was awarded to Otto Paul Hermann Diels and Kurt Alder in 1950.
- Unsaturated polyester resins account for around half of the world's maleic anhydride production.
Recently Updated Pages
Which will be the least stable resonating structure class 11 chemistry CBSE

How many 5 digit telephone numbers can be construc-class-11-maths-CBSE

How do you find the angle of the resultant vector class 11 physics CBSE

Draw labelled diagram of the following i Gram seed class 11 biology CBSE

1 Quintal is equal to a 110 kg b 10 kg c 100kg d 1000 class 11 physics CBSE

What is the need and importance of classification class 11 biology CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

The teeth used for biting and cutting food are called class 11 biology CBSE

