
Given,\[F{e_{0.94}}O\], % of \[F{e^{3 + }}\] ions in the crystal?
Answer
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Hint: Iron paperwork diverse oxide and hydroxide compounds; the maximum not unusual place are iron(II,III) oxide (\[F{e_3}{O_4}\]), and iron(III) oxide (\[F{e_2}{O_3}\]). Iron(II) oxide additionally exists, even though it's miles volatile at room temperature. Despite their names, they may be really all non-stoichiometric compounds whose compositions can also additionally vary. These oxides are the essential ores for the manufacturing of iron. They also are used within the manufacturing of ferrites, beneficial magnetic garage media in computers, and pigments.
Complete answer:
We will start like this, there are no moles for oxygen atoms this means that it is neutral. So the concentration of \[F{e^{2 + }}\] is 0.94-x as we are considering x for \[F{e^{3 + }}\].
The total can be considered as 200 as we have taken 100 for iron and 100 for oxygen. Since oxygen is neutral we are considering it 100 for oxygen and for iron its 94.
\[
3x + 2(94 - x) = 200 \\
3x + 188 - 2x = 200 \\
x + 188 = 200 \\
x = 12 \\
\]
% of \[F{e^{3 + }}\]= \[\dfrac{{12}}{{0.94}} \times 100 = 12.76\% \]
Organo-iron chemistry is the look at organometallic compounds of iron, wherein carbon atoms are covalently sure to the metallic atom. They are many and varied, together with cyanide complexes, carbonyl complexes, sandwich and half-sandwich compounds.
Prussian blue or " ferric ferrocyanide ” , \[F{e_4}{\left[ {Fe{{\left( {CN} \right)}_6}} \right]_3}\], is an antique and famous iron-cyanide complex, significantly used as pigment and in numerous different applications. Its formation may be used as a easy moist chemistry take a look at to differentiate among aqueous answers of \[F{e^{2 + }}\]and \[F{e^{3 + }}\]as they react (respectively) with potassium ferricyanide and potassium ferrocyanide to shape Prussian blue.
Note:
The time period iron is used for extraordinary substances which incorporate an excessive percent of iron in elemental shape. These substances are labeled as (i) natural iron, (ii) wrought iron, (iii) solid iron, (iv) pig iron, and (v) direct decreased iron.
Complete answer:
We will start like this, there are no moles for oxygen atoms this means that it is neutral. So the concentration of \[F{e^{2 + }}\] is 0.94-x as we are considering x for \[F{e^{3 + }}\].
The total can be considered as 200 as we have taken 100 for iron and 100 for oxygen. Since oxygen is neutral we are considering it 100 for oxygen and for iron its 94.
\[
3x + 2(94 - x) = 200 \\
3x + 188 - 2x = 200 \\
x + 188 = 200 \\
x = 12 \\
\]
% of \[F{e^{3 + }}\]= \[\dfrac{{12}}{{0.94}} \times 100 = 12.76\% \]
Organo-iron chemistry is the look at organometallic compounds of iron, wherein carbon atoms are covalently sure to the metallic atom. They are many and varied, together with cyanide complexes, carbonyl complexes, sandwich and half-sandwich compounds.
Prussian blue or " ferric ferrocyanide ” , \[F{e_4}{\left[ {Fe{{\left( {CN} \right)}_6}} \right]_3}\], is an antique and famous iron-cyanide complex, significantly used as pigment and in numerous different applications. Its formation may be used as a easy moist chemistry take a look at to differentiate among aqueous answers of \[F{e^{2 + }}\]and \[F{e^{3 + }}\]as they react (respectively) with potassium ferricyanide and potassium ferrocyanide to shape Prussian blue.
Note:
The time period iron is used for extraordinary substances which incorporate an excessive percent of iron in elemental shape. These substances are labeled as (i) natural iron, (ii) wrought iron, (iii) solid iron, (iv) pig iron, and (v) direct decreased iron.
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