
Give the product of the oxidation of Jones reagent of ${C_6}{H_5}C{H_2}OH$
Answer
516k+ views
Hint: Jones reagent is a solution of chromium trioxide $(Cr{O_3})$ in diluted sulfuric acid in a mixture of acetone and water and can be safely used in acetone for oxidation of organic substances. Jones reagent is also suitable for the oxidation of secondary alcohols to ketones and primary alcohols of carboxylic acids and some aldehydes.
Complete answer:
Jones reagent is an oxidizing agent and when primary alcohol reacts with Jones reagent in an acidic media, oxidation reaction takes place and a carboxylic acid is formed because of the hydration of carbonyl group in the ${H_2}O$ solvent.
Since the given product is ${C_6}{H_5}C{H_2}OH$ and when it reacts with primary alcohol such as${H_2}S{O_4}$, the product formed will be ${C_6}{H_5}COOH$.
The reaction between the given product and Jones reagent is:
Note:
Jones reagent can also be prepared from sodium dichromate and potassium dichromate. Although the reagent is very acidic, the substrate in acetone is essentially titrated with the oxidant solution and only very acid-sensitive groups are incompatible. Potassium dichromate can be used as an alternative to Chromium dichromate. The reagent rarely oxidizes unsaturated bonds and is very rapid, exothermic and are typically high.
Complete answer:
Jones reagent is an oxidizing agent and when primary alcohol reacts with Jones reagent in an acidic media, oxidation reaction takes place and a carboxylic acid is formed because of the hydration of carbonyl group in the ${H_2}O$ solvent.
Since the given product is ${C_6}{H_5}C{H_2}OH$ and when it reacts with primary alcohol such as${H_2}S{O_4}$, the product formed will be ${C_6}{H_5}COOH$.
The reaction between the given product and Jones reagent is:
Note:
Jones reagent can also be prepared from sodium dichromate and potassium dichromate. Although the reagent is very acidic, the substrate in acetone is essentially titrated with the oxidant solution and only very acid-sensitive groups are incompatible. Potassium dichromate can be used as an alternative to Chromium dichromate. The reagent rarely oxidizes unsaturated bonds and is very rapid, exothermic and are typically high.
Recently Updated Pages
Why are manures considered better than fertilizers class 11 biology CBSE

Find the coordinates of the midpoint of the line segment class 11 maths CBSE

Distinguish between static friction limiting friction class 11 physics CBSE

The Chairman of the constituent Assembly was A Jawaharlal class 11 social science CBSE

The first National Commission on Labour NCL submitted class 11 social science CBSE

Number of all subshell of n + l 7 is A 4 B 5 C 6 D class 11 chemistry CBSE

Trending doubts
Differentiate between an exothermic and an endothermic class 11 chemistry CBSE

10 examples of friction in our daily life

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Difference Between Prokaryotic Cells and Eukaryotic Cells

1 Quintal is equal to a 110 kg b 10 kg c 100kg d 1000 class 11 physics CBSE

State the laws of reflection of light

