Answer
Verified
394.5k+ views
Hint: The chemical compounds which have the general formula ${\text{R - Mg - X}}$ where X represents a halogen and R represents an organic group, which may be alkyl or aryl, are termed as ‘Grignard reagents’.
Aliphatic ketones can be prepared by the action of a suitable Grignard reagent on an alkyl nitrile. This method of preparation is useful for preparing ketones only.
Complete step by step answer:
We need to determine what the final product is in the reaction between ethane nitrile and ethyl magnesium bromide.
Ethane nitrile, also known as methyl cyanide or acetonitrile is the simplest organic nitrile and has the molecular formula ${\text{C}}{{\text{H}}_{\text{3}}}{\text{CN}}$ .
Ethyl magnesium bromide is a Grignard reagent having the formula ${\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{MgBr}}$ .
Thus, when ethane nitrile is acted upon by ethyl magnesium bromide, the strongly organometallic reagent adds to the carbon-nitrogen triple bond in a way similar to aldehydes and ketones. The reaction first proceeds through an imine salt intermediate which is then hydrolysed to give butan-2-one.
butan-2-one.
Therefore, option C is correct.
Methoxy propane or methyl propyl ether is an ether, not a ketone. So it cannot be the product of the reaction between a nitrile and a Grignard reagent. So, A is incorrect.
Butanamine is an amine of butane and so it cannot be the product of the reaction between a nitrile and a Grignard reagent. So, B is incorrect.
Pent-2-one is methyl propyl ketone and it will be formed when propyl magnesium bromide reacts with ethane nitrile. So. D is also incorrect.
Hence option C is correct.
Note:
If hydrocyanic acid is used instead of nitrile, then aldehyde is formed.
Aliphatic ketones can be prepared by the action of a suitable Grignard reagent on an alkyl nitrile. This method of preparation is useful for preparing ketones only.
Complete step by step answer:
We need to determine what the final product is in the reaction between ethane nitrile and ethyl magnesium bromide.
Ethane nitrile, also known as methyl cyanide or acetonitrile is the simplest organic nitrile and has the molecular formula ${\text{C}}{{\text{H}}_{\text{3}}}{\text{CN}}$ .
Ethyl magnesium bromide is a Grignard reagent having the formula ${\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{MgBr}}$ .
Thus, when ethane nitrile is acted upon by ethyl magnesium bromide, the strongly organometallic reagent adds to the carbon-nitrogen triple bond in a way similar to aldehydes and ketones. The reaction first proceeds through an imine salt intermediate which is then hydrolysed to give butan-2-one.
butan-2-one.
Therefore, option C is correct.
Methoxy propane or methyl propyl ether is an ether, not a ketone. So it cannot be the product of the reaction between a nitrile and a Grignard reagent. So, A is incorrect.
Butanamine is an amine of butane and so it cannot be the product of the reaction between a nitrile and a Grignard reagent. So, B is incorrect.
Pent-2-one is methyl propyl ketone and it will be formed when propyl magnesium bromide reacts with ethane nitrile. So. D is also incorrect.
Hence option C is correct.
Note:
If hydrocyanic acid is used instead of nitrile, then aldehyde is formed.
Recently Updated Pages
Basicity of sulphurous acid and sulphuric acid are
Three beakers labelled as A B and C each containing 25 mL of water were taken A small amount of NaOH anhydrous CuSO4 and NaCl were added to the beakers A B and C respectively It was observed that there was an increase in the temperature of the solutions contained in beakers A and B whereas in case of beaker C the temperature of the solution falls Which one of the following statements isarecorrect i In beakers A and B exothermic process has occurred ii In beakers A and B endothermic process has occurred iii In beaker C exothermic process has occurred iv In beaker C endothermic process has occurred
What is the stopping potential when the metal with class 12 physics JEE_Main
The momentum of a photon is 2 times 10 16gm cmsec Its class 12 physics JEE_Main
How do you arrange NH4 + BF3 H2O C2H2 in increasing class 11 chemistry CBSE
Is H mCT and q mCT the same thing If so which is more class 11 chemistry CBSE
Trending doubts
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Write an application to the principal requesting five class 10 english CBSE
Difference Between Plant Cell and Animal Cell
a Tabulate the differences in the characteristics of class 12 chemistry CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
What organs are located on the left side of your body class 11 biology CBSE
Discuss what these phrases mean to you A a yellow wood class 9 english CBSE
List some examples of Rabi and Kharif crops class 8 biology CBSE