Question

Explain the important aspects of resonance with reference to the ${ CO }_{ 3 }^{ 2- }$ ion.

Answer 1

Hint: Resonance: It is defined as the transfer of electrons from multiple bonds or a lone pair of electrons from an atom to another atom or to an adjacent single covalent bond.

Complete step-by-step answer:
Resonance can be defined as the phenomenon of the existence of a molecule in many structures due to the delocalization of electrons. These structures are similar in energy, bonding, and nonbonding pairs of electrons. Only the distribution of electrons is different. In other words, if a molecule or an ion can be shown by ${ 2 }$ or more structures differing only in the distribution of electrons (but are otherwise the same in terms of number of electrons, energy, bonding atoms, etc), then the phenomenon is called resonance. These different structures of the molecule are called resonating, canonical, or contributing structures and none of them truly explain all the properties of the molecule or ion.
Thus a resonance structure is nothing but an alternate way of drawing a Lewis dot structure for a compound. There are many ways to draw a Lewis dot structure for some molecules that still satisfy the rules (for instance, satisfying the octet rule on each atom & having the correct total electron count).
Now let us consider drawing different resonating structures with the help of carbonate ion ${ CO }_{ 3 }^{ 2- }$. Resonating structures of this ion are represented as follows;

Figure: Resonating structures of carbonate ion

Here the central oxygen atom is bonded to three oxygen atoms. As these atoms are chemically identical, therefore any of these atoms can carry a negative charge or can be bonded to the carbon atoms by a double bond. In other words, the negative charge can reside on any of the oxygen atoms. Thus these structures differ only in the distribution of electrons but are otherwise the same. Hence, in each resonating structure, each separate oxygen atom will be bonded by a double bond, while the remaining two oxygen atoms will possess a negative charge.

Note: The possibility to make a mistake is that the negative charge persists on one oxygen atom but the atoms are identical, so any of these atoms can carry a negative charge.