Ethane nitrile to ethanol: convert?
Answer
552k+ views
Hint: Chemical compounds can be classified based on the functional groups attached to it. Nitriles are the chemical compounds consisting of a functional group \[ - CN\] . Nitriles are also known as cyanides. Nitriles can be converted into ethanol by hydrolysis followed by reduction by strong reducing agents.
Complete answer:
Cyanides are also known as nitriles consisting of a functional group \[ - CN\]the alkyl group is attached to the cyanide group. Ethane nitrile is a chemical compound with the molecular formula of \[C{H_3}CN\] it consists of methyl group and cyanide group. When hydrolysis is done to the cyanide compound, the \[ - CN\] group converts into \[ - COOH\] group.
Ethane nitrile can be converted into acetic acid by hydrolysis. As cyanides can be converted into acids by acidic hydrolysis. The product of acetic acid when treated with lithium aluminium hydride forms ethanol. When reduction is done with lithium aluminium hydride the \[ - COOH\] group turns into \[ - C{H_2}OH\]
Lithium aluminium hydride is a strong reducing agent with the molecular formula of \[LiAl{H_4}\] it belongs to the hydride family as the \[{H^ - }\] is present in the lithium aluminium hydride. Lithium aluminium hydride is used for reduction of other compounds.
The chemical reaction for the conversion of ethane nitrile to ethanol is as follows:
\[C{H_3}C \equiv N\xrightarrow{{{H_3}{O^ + }}}C{H_3}COOH\xrightarrow{{LiAl{H_4}}}C{H_3}C{H_2}OH\]
Note:
Only strong reducing agents like lithium aluminium hydride \[\left( {LiAl{H_4}} \right)\] and sodium borohydride \[\left( {NaB{H_4}} \right)\] which are belongs to the hydride family can be used for the reduction of nitriles to carboxylic acids as moderate reducing agents can reduce the nitriles to carbonyl compounds means aldehydes or ketones.
Complete answer:
Cyanides are also known as nitriles consisting of a functional group \[ - CN\]the alkyl group is attached to the cyanide group. Ethane nitrile is a chemical compound with the molecular formula of \[C{H_3}CN\] it consists of methyl group and cyanide group. When hydrolysis is done to the cyanide compound, the \[ - CN\] group converts into \[ - COOH\] group.
Ethane nitrile can be converted into acetic acid by hydrolysis. As cyanides can be converted into acids by acidic hydrolysis. The product of acetic acid when treated with lithium aluminium hydride forms ethanol. When reduction is done with lithium aluminium hydride the \[ - COOH\] group turns into \[ - C{H_2}OH\]
Lithium aluminium hydride is a strong reducing agent with the molecular formula of \[LiAl{H_4}\] it belongs to the hydride family as the \[{H^ - }\] is present in the lithium aluminium hydride. Lithium aluminium hydride is used for reduction of other compounds.
The chemical reaction for the conversion of ethane nitrile to ethanol is as follows:
\[C{H_3}C \equiv N\xrightarrow{{{H_3}{O^ + }}}C{H_3}COOH\xrightarrow{{LiAl{H_4}}}C{H_3}C{H_2}OH\]
Note:
Only strong reducing agents like lithium aluminium hydride \[\left( {LiAl{H_4}} \right)\] and sodium borohydride \[\left( {NaB{H_4}} \right)\] which are belongs to the hydride family can be used for the reduction of nitriles to carboxylic acids as moderate reducing agents can reduce the nitriles to carbonyl compounds means aldehydes or ketones.
Recently Updated Pages
Lysosomes are known as suicidal bags of cell why class 11 biology CBSE

Father s age is three times the sum of the ages of-class-11-maths-CBSE

Give a comparative account of the classes of kingdom class 11 biology CBSE

The ceiling of a long hall is 25m high What is the class 11 physics CBSE

Name the Largest and the Smallest Cell in the Human Body ?

Draw a welllabelled diagram of a plant cell class 11 biology CBSE

Trending doubts
Find the value of the expression given below sin 30circ class 11 maths CBSE

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Two of the body parts which do not appear in MRI are class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

10 examples of diffusion in everyday life

