
Diazo coupling is useful to prepare some:
(a)- Pesticides
(b)- Dyes
(c)- Proteins
(d)- Vitamins
Answer
578.1k+ views
Hint: The product formed by the diazo coupling reaction is a colored compound and is used to color other compounds. Methyl orange is an example of a compound formed by the diazo coupling reaction.
Complete answer:
Arenediazonium salts react with highly reactive (i.e., electron-rich) aromatic compounds such as phenols and amines to form highly brightly colored azo compounds $Ar-N=N-Ar$. This reaction is called a coupling reaction and is extensively used in the azo dye industry. Whereas coupling with phenols occurs in the basic medium (pH 9-10) that of amines occurs in the faintly acidic medium at 273-278 K.
The color of azo compounds is due to extended conjugation involving the double bonds of both the arene (benzene) rings through a $-N=N-$ double bond.
A coupling reaction is an example of an electrophilic substitution reaction in which the diazonium cation with the positive charge on the terminal nitrogen acts as the electrophile while the electron-rich compound such as phenols and amines acts as the nucleophile.
When benzene diazonium chloride reacts with phenol it forms p-Hydroxyazobenzene which is an orange dye.
The reaction is given below:
When benzene diazonium chloride reacts with aniline it forms p-Aminoazobenzene which is a yellow dye.
The reaction is given below:
Hence, the correct answer is an option (b)- Dyes.
Note:
The well-known indicator methyl orange which is widely used in acid-base titrations is obtained by coupling the diazonium salt of sulfanilic acid with N, N-dimethylaniline.
The reaction is:
Complete answer:
Arenediazonium salts react with highly reactive (i.e., electron-rich) aromatic compounds such as phenols and amines to form highly brightly colored azo compounds $Ar-N=N-Ar$. This reaction is called a coupling reaction and is extensively used in the azo dye industry. Whereas coupling with phenols occurs in the basic medium (pH 9-10) that of amines occurs in the faintly acidic medium at 273-278 K.
The color of azo compounds is due to extended conjugation involving the double bonds of both the arene (benzene) rings through a $-N=N-$ double bond.
A coupling reaction is an example of an electrophilic substitution reaction in which the diazonium cation with the positive charge on the terminal nitrogen acts as the electrophile while the electron-rich compound such as phenols and amines acts as the nucleophile.
When benzene diazonium chloride reacts with phenol it forms p-Hydroxyazobenzene which is an orange dye.
The reaction is given below:
When benzene diazonium chloride reacts with aniline it forms p-Aminoazobenzene which is a yellow dye.
The reaction is given below:
Hence, the correct answer is an option (b)- Dyes.
Note:
The well-known indicator methyl orange which is widely used in acid-base titrations is obtained by coupling the diazonium salt of sulfanilic acid with N, N-dimethylaniline.
The reaction is:
Recently Updated Pages
Why are manures considered better than fertilizers class 11 biology CBSE

Find the coordinates of the midpoint of the line segment class 11 maths CBSE

Distinguish between static friction limiting friction class 11 physics CBSE

The Chairman of the constituent Assembly was A Jawaharlal class 11 social science CBSE

The first National Commission on Labour NCL submitted class 11 social science CBSE

Number of all subshell of n + l 7 is A 4 B 5 C 6 D class 11 chemistry CBSE

Trending doubts
10 examples of friction in our daily life

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Difference Between Prokaryotic Cells and Eukaryotic Cells

1 Quintal is equal to a 110 kg b 10 kg c 100kg d 1000 class 11 physics CBSE

State the laws of reflection of light

Explain zero factorial class 11 maths CBSE

