
What determines the nucleophile’s strength?
Answer
523.8k+ views
Hint: A nucleophile is a kind of chemical species that donate electron pairs to electrophiles. By this sharing and taking up of electrons a chemical bond is formed between them.
Complete step by step answer:
Nucleophiles are electron rich species and hence they can donate electrons to form bonds and therefore, they are also known as Lewis bases.
Nucleophilicity is the nucleophilic character of different nucleophiles. This can also be known as nucleophilic strength.
So, nucleophiles are leaving groups and their relative strength is nucleophilic strength.
It depends on various factors such as polarizability, solvent, charge, basicity, or nature of substitutes.
Nucleophiles can be neutral or negatively charged but it should have electrons to donate. But increasing the negative charge increases nucleophilicity like N in $N{{H}_{2}}$ is a better nucleophile than N in $N{{H}_{3}}$ since it is negatively charged there.
As basicity decreases from left to right in a period so does nucleophilicity. But exceptions are always there like while moving from top to bottom in a group in halogens they do not follow basicity behavior.
Depending upon the type of solvent polar non polar protic aprotic nucleophilicity varies. In aprotic solvents nucleophilicity increases down the group while in aprotic it decreases down the group.
Nucleophilicity increases with increase in atomic size because larger elements diffuse and polarized electron clouds easily.
Nucleophilicity is hindered due to steric hindrance.
Note: We have seen that nucleophilicity is dependent on a lot of factors but at the same time all these factors can vary depending upon the type of nucleophile their chemical composition and structure.
Complete step by step answer:
Nucleophiles are electron rich species and hence they can donate electrons to form bonds and therefore, they are also known as Lewis bases.
Nucleophilicity is the nucleophilic character of different nucleophiles. This can also be known as nucleophilic strength.
So, nucleophiles are leaving groups and their relative strength is nucleophilic strength.
It depends on various factors such as polarizability, solvent, charge, basicity, or nature of substitutes.
Nucleophiles can be neutral or negatively charged but it should have electrons to donate. But increasing the negative charge increases nucleophilicity like N in $N{{H}_{2}}$ is a better nucleophile than N in $N{{H}_{3}}$ since it is negatively charged there.
As basicity decreases from left to right in a period so does nucleophilicity. But exceptions are always there like while moving from top to bottom in a group in halogens they do not follow basicity behavior.
Depending upon the type of solvent polar non polar protic aprotic nucleophilicity varies. In aprotic solvents nucleophilicity increases down the group while in aprotic it decreases down the group.
Nucleophilicity increases with increase in atomic size because larger elements diffuse and polarized electron clouds easily.
Nucleophilicity is hindered due to steric hindrance.
Note: We have seen that nucleophilicity is dependent on a lot of factors but at the same time all these factors can vary depending upon the type of nucleophile their chemical composition and structure.
Recently Updated Pages
Why are manures considered better than fertilizers class 11 biology CBSE

Find the coordinates of the midpoint of the line segment class 11 maths CBSE

Distinguish between static friction limiting friction class 11 physics CBSE

The Chairman of the constituent Assembly was A Jawaharlal class 11 social science CBSE

The first National Commission on Labour NCL submitted class 11 social science CBSE

Number of all subshell of n + l 7 is A 4 B 5 C 6 D class 11 chemistry CBSE

Trending doubts
Differentiate between an exothermic and an endothermic class 11 chemistry CBSE

10 examples of friction in our daily life

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Difference Between Prokaryotic Cells and Eukaryotic Cells

State the laws of reflection of light

Explain zero factorial class 11 maths CBSE

