
What determines the nucleophile’s strength?
Answer
526.5k+ views
Hint: A nucleophile is a kind of chemical species that donate electron pairs to electrophiles. By this sharing and taking up of electrons a chemical bond is formed between them.
Complete step by step answer:
Nucleophiles are electron rich species and hence they can donate electrons to form bonds and therefore, they are also known as Lewis bases.
Nucleophilicity is the nucleophilic character of different nucleophiles. This can also be known as nucleophilic strength.
So, nucleophiles are leaving groups and their relative strength is nucleophilic strength.
It depends on various factors such as polarizability, solvent, charge, basicity, or nature of substitutes.
Nucleophiles can be neutral or negatively charged but it should have electrons to donate. But increasing the negative charge increases nucleophilicity like N in $N{{H}_{2}}$ is a better nucleophile than N in $N{{H}_{3}}$ since it is negatively charged there.
As basicity decreases from left to right in a period so does nucleophilicity. But exceptions are always there like while moving from top to bottom in a group in halogens they do not follow basicity behavior.
Depending upon the type of solvent polar non polar protic aprotic nucleophilicity varies. In aprotic solvents nucleophilicity increases down the group while in aprotic it decreases down the group.
Nucleophilicity increases with increase in atomic size because larger elements diffuse and polarized electron clouds easily.
Nucleophilicity is hindered due to steric hindrance.
Note: We have seen that nucleophilicity is dependent on a lot of factors but at the same time all these factors can vary depending upon the type of nucleophile their chemical composition and structure.
Complete step by step answer:
Nucleophiles are electron rich species and hence they can donate electrons to form bonds and therefore, they are also known as Lewis bases.
Nucleophilicity is the nucleophilic character of different nucleophiles. This can also be known as nucleophilic strength.
So, nucleophiles are leaving groups and their relative strength is nucleophilic strength.
It depends on various factors such as polarizability, solvent, charge, basicity, or nature of substitutes.
Nucleophiles can be neutral or negatively charged but it should have electrons to donate. But increasing the negative charge increases nucleophilicity like N in $N{{H}_{2}}$ is a better nucleophile than N in $N{{H}_{3}}$ since it is negatively charged there.
As basicity decreases from left to right in a period so does nucleophilicity. But exceptions are always there like while moving from top to bottom in a group in halogens they do not follow basicity behavior.
Depending upon the type of solvent polar non polar protic aprotic nucleophilicity varies. In aprotic solvents nucleophilicity increases down the group while in aprotic it decreases down the group.
Nucleophilicity increases with increase in atomic size because larger elements diffuse and polarized electron clouds easily.
Nucleophilicity is hindered due to steric hindrance.
Note: We have seen that nucleophilicity is dependent on a lot of factors but at the same time all these factors can vary depending upon the type of nucleophile their chemical composition and structure.
Recently Updated Pages
The number of solutions in x in 02pi for which sqrt class 12 maths CBSE

Write any two methods of preparation of phenol Give class 12 chemistry CBSE

Differentiate between action potential and resting class 12 biology CBSE

Two plane mirrors arranged at right angles to each class 12 physics CBSE

Which of the following molecules is are chiral A I class 12 chemistry CBSE

Name different types of neurons and give one function class 12 biology CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

What is 1s 2s 2p 3s 3p class 11 chemistry CBSE

Discuss the various forms of bacteria class 11 biology CBSE

State the laws of reflection of light

Explain zero factorial class 11 maths CBSE

An example of chemosynthetic bacteria is A E coli B class 11 biology CBSE

