What is dehydrohalogenation reaction?
Answer
599.7k+ views
Hint:Dehydrogenation or dehydration describes the removal of hydrogen atoms whereas, dehalogenation describes the removal of halogens. Therefore, as the name suggests, dehydrohalogenation suggests the removal of hydrogen and a halogen group.
Complete step-by-step answer:Let us describe the dehydrohalogenation in detail;
Dehydrohalogenation reaction-
It is in general, the synthesis reaction of alkene (or alkyne) from alkyl halides; by the elimination of HX (H represents hydrogen and X represents halogen) from adjacent atoms.
The alkyl halides or haloalkanes are usually the bromo- or iodo- or less commonly chloro- substituted alkanes.
It is normally carried out in methanol with sodium methoxide, in ethanol with sodium ethoxide or in tert-butyl alcohol with potassium tert-butoxide; along with the presence of heat.
One of the reactions can be represented as;
n-butyl chloride gets converted to but-1-ene in the presence of alcoholic KOH.
$C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}Cl\xrightarrow[Heat]{KOH\left( alc. \right)}C{{H}_{3}}C{{H}_{2}}CH=C{{H}_{2}}$
Note: Do note that this reaction would be more precise if we call it a beta-dehydrohalogenation reaction as the hydrogen is being removed from the beta carbon i.e. the adjacent carbon to the carbon, halogen is attached.
Also, if more than one alkene is produced during the reaction then, more substituted alkene is the major product of the reaction.
Complete step-by-step answer:Let us describe the dehydrohalogenation in detail;
Dehydrohalogenation reaction-
It is in general, the synthesis reaction of alkene (or alkyne) from alkyl halides; by the elimination of HX (H represents hydrogen and X represents halogen) from adjacent atoms.
The alkyl halides or haloalkanes are usually the bromo- or iodo- or less commonly chloro- substituted alkanes.
It is normally carried out in methanol with sodium methoxide, in ethanol with sodium ethoxide or in tert-butyl alcohol with potassium tert-butoxide; along with the presence of heat.
One of the reactions can be represented as;
n-butyl chloride gets converted to but-1-ene in the presence of alcoholic KOH.
$C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}Cl\xrightarrow[Heat]{KOH\left( alc. \right)}C{{H}_{3}}C{{H}_{2}}CH=C{{H}_{2}}$
Note: Do note that this reaction would be more precise if we call it a beta-dehydrohalogenation reaction as the hydrogen is being removed from the beta carbon i.e. the adjacent carbon to the carbon, halogen is attached.
Also, if more than one alkene is produced during the reaction then, more substituted alkene is the major product of the reaction.
Recently Updated Pages
Lysosomes are known as suicidal bags of cell why class 11 biology CBSE

Father s age is three times the sum of the ages of-class-11-maths-CBSE

Give a comparative account of the classes of kingdom class 11 biology CBSE

The ceiling of a long hall is 25m high What is the class 11 physics CBSE

Name the Largest and the Smallest Cell in the Human Body ?

Draw a welllabelled diagram of a plant cell class 11 biology CBSE

Trending doubts
Find the value of the expression given below sin 30circ class 11 maths CBSE

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

10 examples of friction in our daily life

Draw a diagram of nephron and explain its structur class 11 biology CBSE

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

Frogs heart when taken out of the body continues to class 11 biology CBSE

