
Benzene can be conveniently converted into n-propyl benzene by:
A.Friedel-craft alkylation with n-propyl chloride.
B.Friedel-Craft acylation with propionyl chloride followed by Wolff-Kishner reduction.
C.Friedel-Craft acylation with propionyl chloride followed by catalytic hydrogenation.
D.Friedel-Craft acylation with propionyl chloride followed by reduction with
Answer
508.5k+ views
1 likes
Hint: Preparation of n-propylbenzene from Benzene is a two-step process. We cannot prepare n-propylbenzene from benzene in a single step. In the first step benzene reacts with propionyl chloride and then undergoes reduction with hydrazine.
Complete answer:
The preparation of n-propyl benzene from benzene is as follows.
Step-1: Friedel-craft acylation:
Reaction of Benzene with propionyl chloride is called Friedel-craft acylation reaction. Because the acyl group is going to be added to benzene.
Step-2: Wolff-Kishner reduction:
In this reaction propionyl benzene reacts with hydrazine and forms a hydrazine derivative. This reaction is called Wolff-Kishner reduction.
Followed by Wolff-Kishner reduction, reaction with KOH, ethylene glycol forms n-propyl benzene.
Therefore, the preparation of n-propyl benzene from benzene involves Friedel-Craft acylation with propionyl chloride followed by Wolff-Kishner reduction.
So, the correct option is B.
Note:
We are not supposed to use catalytic hydrogenation or reduction with lithium aluminum hydride ( ) in step-2. Because catalytic hydrogen or reduction with aluminum hydride ( ) may cause reduction on the benzene ring. So, we are not supposed to use these reducing agents in the step-2. Wolff-Kishner reduction is the best way to reduce carbonyl carbon without disturbing the structure of the benzene.
Complete answer:
The preparation of n-propyl benzene from benzene is as follows.
Step-1: Friedel-craft acylation:
Reaction of Benzene with propionyl chloride is called Friedel-craft acylation reaction. Because the acyl group is going to be added to benzene.

Step-2: Wolff-Kishner reduction:
In this reaction propionyl benzene reacts with hydrazine and forms a hydrazine derivative. This reaction is called Wolff-Kishner reduction.

Followed by Wolff-Kishner reduction, reaction with KOH, ethylene glycol forms n-propyl benzene.

Therefore, the preparation of n-propyl benzene from benzene involves Friedel-Craft acylation with propionyl chloride followed by Wolff-Kishner reduction.
So, the correct option is B.
Note:
We are not supposed to use catalytic hydrogenation or reduction with lithium aluminum hydride (
Latest Vedantu courses for you
Grade 10 | MAHARASHTRABOARD | SCHOOL | English
Vedantu 10 Maharashtra Pro Lite (2025-26)
School Full course for MAHARASHTRABOARD students
₹33,300 per year
Recently Updated Pages
Master Class 11 Accountancy: Engaging Questions & Answers for Success

Master Class 11 Social Science: Engaging Questions & Answers for Success

Master Class 11 Economics: Engaging Questions & Answers for Success

Master Class 11 Physics: Engaging Questions & Answers for Success

Master Class 11 Biology: Engaging Questions & Answers for Success

Class 11 Question and Answer - Your Ultimate Solutions Guide

Trending doubts
Explain why it is said like that Mock drill is use class 11 social science CBSE

The non protein part of an enzyme is a A Prosthetic class 11 biology CBSE

Which of the following blood vessels in the circulatory class 11 biology CBSE

What is a zygomorphic flower Give example class 11 biology CBSE

1 ton equals to A 100 kg B 1000 kg C 10 kg D 10000 class 11 physics CBSE

The deoxygenated blood from the hind limbs of the frog class 11 biology CBSE
