
An alcohol used as an antifreeze compound is ethylene glycol.
A. True
B. False
Answer
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Hint: Alcohol is an organic compound in which the hydroxyl group is bound with a saturated carbon atom. Primary alcohol(ethanol) is used as a drug. Based on the number of \[ - OH\] groups there are two kinds of alcohol, one is gem diol and the other one is a vicinal diol.
Complete step by step answer:
Ethylene glycol is a vicinal diol. The IUPAC name is ethylene 1,2 diol. It is used as a Raw material to synthesis polyester fibers. For example, terylene fiber is a synthetic polymer. It is produced by the condensation reaction mechanism between ethylene glycol and terephthalic acid. The reaction is shown below,
Among alcohols, this compound can be used as the anti-frozen compound. It can decrease the freezing point of the substance. The structure of ethylene glycol is,
So, the given statement is true.
The correct option is A.
Additional information:
When the two \[ - OH\] groups are attached at the same carbon of the organic compound then it is called gem diol. And when the \[ - OH\] groups are in two different but neighboring carbon then it is called vicinal diol.
The gem diols are less stable than vicinal diols
The stability of gem diols can be increased in the presence of the electron-withdrawing group at the alpha position. +I effect decreases the stability of the gem diol and increases the extent of dehydration as follows.
And -I effect increases the stability of gem diol. As well as the intramolecular hydrogen bonding also increases the stability of gem diol.
Note:The vicinal diols can be formed by oxidation of the double bonds. For example, when acidified \[\;KMn{O_4}\] reacts with cyclohexene oxidation of the double bonds takes place and vicinal diol is formed as follows,
Complete step by step answer:
Ethylene glycol is a vicinal diol. The IUPAC name is ethylene 1,2 diol. It is used as a Raw material to synthesis polyester fibers. For example, terylene fiber is a synthetic polymer. It is produced by the condensation reaction mechanism between ethylene glycol and terephthalic acid. The reaction is shown below,
Among alcohols, this compound can be used as the anti-frozen compound. It can decrease the freezing point of the substance. The structure of ethylene glycol is,
So, the given statement is true.
The correct option is A.
Additional information:
When the two \[ - OH\] groups are attached at the same carbon of the organic compound then it is called gem diol. And when the \[ - OH\] groups are in two different but neighboring carbon then it is called vicinal diol.
The gem diols are less stable than vicinal diols
The stability of gem diols can be increased in the presence of the electron-withdrawing group at the alpha position. +I effect decreases the stability of the gem diol and increases the extent of dehydration as follows.
And -I effect increases the stability of gem diol. As well as the intramolecular hydrogen bonding also increases the stability of gem diol.
Note:The vicinal diols can be formed by oxidation of the double bonds. For example, when acidified \[\;KMn{O_4}\] reacts with cyclohexene oxidation of the double bonds takes place and vicinal diol is formed as follows,
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