
What is a non-conjugated ketone and what is a conjugated ketone?
Answer
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Hint :We know that the non-aromatic or aromatic compounds can be checked by certain rules, if it follows then, aromatic and if not then, not aromatic. Aromaticity is a special property which is seen in organic compounds of ring-shaped, flat structures with a ring of conjugated systems that gives increased stability.
Complete Step By Step Answer:
An aromatic compound contains a set of covalent bonds with specific characteristics a delocalized conjugated system of electrons, which is an arrangement of alternating single and double bonds. It should be a coplanar structure having all the atoms in the same plane. It should follow Huckel’s rule, a number of delocalized electrons. In a conjugated system, electrons are delocalized with the alternate single and double bond. Lone pairs can also be part of the system.
Conjugated ketone has a $ C=C $ unit attached directly to carbon of the carbonyl group. While in Non-conjugated ketones the carbonyl group don't contact with any $ C=C $ unit $ C{{H}_{2}}=CH-C\left( O \right)-C{{H}_{3~}} $ is a simple conjugate ketone (the Carbon atom connected to the Carbon atom of the carbonyl group forms a double bond to another carbon atom while $ C{{H}_{2}}=CH-C{{H}_{2}}-C\left( O \right)-C{{H}_{3}} $ would be non-conjugate because the Carbon atoms forming the double bond don't contact the carbonyl group directly.
Note :
Remember that the compound’s’ does not seem to be aromatic by its structure because the ring has electrons, which does not satisfy Huckel’s rule. But on resonance, with other atoms, a resonating structure is formed which is aromatic. So, do not judge Aromaticity by just looking at the compound, it can be aromatic in one form or another.
Complete Step By Step Answer:
An aromatic compound contains a set of covalent bonds with specific characteristics a delocalized conjugated system of electrons, which is an arrangement of alternating single and double bonds. It should be a coplanar structure having all the atoms in the same plane. It should follow Huckel’s rule, a number of delocalized electrons. In a conjugated system, electrons are delocalized with the alternate single and double bond. Lone pairs can also be part of the system.
Conjugated ketone has a $ C=C $ unit attached directly to carbon of the carbonyl group. While in Non-conjugated ketones the carbonyl group don't contact with any $ C=C $ unit $ C{{H}_{2}}=CH-C\left( O \right)-C{{H}_{3~}} $ is a simple conjugate ketone (the Carbon atom connected to the Carbon atom of the carbonyl group forms a double bond to another carbon atom while $ C{{H}_{2}}=CH-C{{H}_{2}}-C\left( O \right)-C{{H}_{3}} $ would be non-conjugate because the Carbon atoms forming the double bond don't contact the carbonyl group directly.
Note :
Remember that the compound’s’ does not seem to be aromatic by its structure because the ring has electrons, which does not satisfy Huckel’s rule. But on resonance, with other atoms, a resonating structure is formed which is aromatic. So, do not judge Aromaticity by just looking at the compound, it can be aromatic in one form or another.
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