
write the IUPAC name of the compound in the picture.
Answer
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Hint: The IUPAC nomenclature of organic chemistry is a system of organic chemical compounds in the nomenclature of chemicals as stated by the International Union of Pure and Applied Chemistry. Informally we call it Blue Book. The book mentions certain rules for the naming of compounds having functional groups.
Complete step by step answer:
Benzene is an aromatic compound with the formula \[{C_6}{H_6}\]. When one or more than one hydrogens of benzene are replaced by any groups then several compounds are formed. Now for the IUPAC nomenclature at first, we prefix the name of a substituent to the word benzene. For example, chlorobenzene, methylbenzene, etc.
Now when more than one group is present, at first find out the main compound then give the number to other groups in such a way that they get fewer numbers. Or if there is now base compound then give numbers according to the alphabetical order.
If organic compounds contain one principal functional group then the longest continuous chain of carbon atoms having that functional group is selected. Functional groups are specific substituents in the molecules that are responsible for the characteristic chemical reactions of those molecules.
In the IUPAC nomenclature case, the root word is the number of total carbons in the longest chain of that compound.
… and so on.
The primary suffix is used to differentiate between the saturated compounds (Alkanes) and unsaturated compounds (Alkene and Alkynes).
If there is more than one suffix. Then one of those suffixes is considered as the secondary suffix.
Example: Methanol (Alkanol), here ‘ol’ is a secondary suffix.
The primary prefixes are used to differentiate between cyclic compounds and noncyclic or chain compounds. For cyclic compound prefix s ‘cyclo’. if there are any side chains or groups are present then secondary prefixes like ‘methyl’, ‘ethyl’, ‘propyl’, ‘isopropyl’ are used.
Now from the question, the compound is,
The IUPAC name of the compound is 1-Benzyl -3, 3 - dimethylprop-1-ene - 3 – ol.
Note: One must remember that every substituent should have a number and in the case of aromatic compounds, the positions concerning the first one is known as ortho \[\left( {1,2;1,6} \right)\], meta \[\left( {1,3;1,5} \right)\], and para \[\left( {1,4} \right)\]. Use of commas to separate numbers and hyphens to separate numbers and substituents is done while writing the formula.
Complete step by step answer:
Benzene is an aromatic compound with the formula \[{C_6}{H_6}\]. When one or more than one hydrogens of benzene are replaced by any groups then several compounds are formed. Now for the IUPAC nomenclature at first, we prefix the name of a substituent to the word benzene. For example, chlorobenzene, methylbenzene, etc.
Now when more than one group is present, at first find out the main compound then give the number to other groups in such a way that they get fewer numbers. Or if there is now base compound then give numbers according to the alphabetical order.
If organic compounds contain one principal functional group then the longest continuous chain of carbon atoms having that functional group is selected. Functional groups are specific substituents in the molecules that are responsible for the characteristic chemical reactions of those molecules.
In the IUPAC nomenclature case, the root word is the number of total carbons in the longest chain of that compound.
| No. of carbons | Root word |
| 1 | meth |
| 2 | eth |
| 3 | prop |
| 4 | but |
| 5 | pent |
… and so on.
The primary suffix is used to differentiate between the saturated compounds (Alkanes) and unsaturated compounds (Alkene and Alkynes).
| compound | suffix |
| Alkane | ane |
| Alkene | Ene |
| Alkyne | Yne |
If there is more than one suffix. Then one of those suffixes is considered as the secondary suffix.
Example: Methanol (Alkanol), here ‘ol’ is a secondary suffix.
The primary prefixes are used to differentiate between cyclic compounds and noncyclic or chain compounds. For cyclic compound prefix s ‘cyclo’. if there are any side chains or groups are present then secondary prefixes like ‘methyl’, ‘ethyl’, ‘propyl’, ‘isopropyl’ are used.
Now from the question, the compound is,
The IUPAC name of the compound is 1-Benzyl -3, 3 - dimethylprop-1-ene - 3 – ol.
Note: One must remember that every substituent should have a number and in the case of aromatic compounds, the positions concerning the first one is known as ortho \[\left( {1,2;1,6} \right)\], meta \[\left( {1,3;1,5} \right)\], and para \[\left( {1,4} \right)\]. Use of commas to separate numbers and hyphens to separate numbers and substituents is done while writing the formula.
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