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Hint: The formal charge is the difference in the number of valence electrons in the atom and the number of valence electrons in the Lewis structure.
Complete answer step-by-step:
The formal charge of an atom in a molecule can be calculated by the following equation;
${ FC=V-N-B\div 2 }$
where V= number of valence electrons of the atom in the free atom
N = number of nonbonding electrons on this atom in the molecule
B = Total number of electrons shared in covalent bonds with other atoms in the molecule.
Nitrogen in the nitro group ${ NO }_{ 2 }^{ - }$ : FC= ${ 5-2-6\div 2=0 }$
Double bonded oxygen in ${ NO }_{ 2 }^{ - }$ : FC=${ 6-4-4\div 2=0 }$
Single bonded oxygen in ${ NO }_{ 2 }^{ - }$ : FC= ${ 6-6-2\div 2=-1 }$
Hence, ${ 0+0+(-1)=-1 }$ as expected for ${ NO }_{ 2 }^{ - }$
Additional Information:
Formal charge means ignore the lone pair of electrons and electrons shared by that atom from valence electrons then whatever is left with you is the significance of formal charge.
- It helps us to keep track of the electrons in a molecule.
- It tells you whether an atom has more electrons or protons associated with it.
- It allows us to assign electrons to a particular atom in a molecule.
Note: The possibility to make a mistake is that you may confuse between formal charge and the actual charge. But keep in mind that formal charges do not represent the actual charge on atoms in a molecule. The formal charges are assigned to the atoms in the Lewis structure to keep track of the electrons involved in the bonding.
Complete answer step-by-step:
The formal charge of an atom in a molecule can be calculated by the following equation;
${ FC=V-N-B\div 2 }$
where V= number of valence electrons of the atom in the free atom
N = number of nonbonding electrons on this atom in the molecule
B = Total number of electrons shared in covalent bonds with other atoms in the molecule.
Nitrogen in the nitro group ${ NO }_{ 2 }^{ - }$ : FC= ${ 5-2-6\div 2=0 }$
Double bonded oxygen in ${ NO }_{ 2 }^{ - }$ : FC=${ 6-4-4\div 2=0 }$
Single bonded oxygen in ${ NO }_{ 2 }^{ - }$ : FC= ${ 6-6-2\div 2=-1 }$
Hence, ${ 0+0+(-1)=-1 }$ as expected for ${ NO }_{ 2 }^{ - }$
Additional Information:
Formal charge means ignore the lone pair of electrons and electrons shared by that atom from valence electrons then whatever is left with you is the significance of formal charge.
- It helps us to keep track of the electrons in a molecule.
- It tells you whether an atom has more electrons or protons associated with it.
- It allows us to assign electrons to a particular atom in a molecule.
Note: The possibility to make a mistake is that you may confuse between formal charge and the actual charge. But keep in mind that formal charges do not represent the actual charge on atoms in a molecule. The formal charges are assigned to the atoms in the Lewis structure to keep track of the electrons involved in the bonding.
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