Question

What are Aromatic hydrocarbons?

Answer 1

Hint: Hydrocarbons are organic compounds mainly consisting of carbon atom chains or rings through single, double or triple bonds. The hydrocarbons containing single bonds only are called saturated hydrocarbons and the ones with double bonds are called unsaturated hydrocarbons and aromatic hydrocarbons are special unsaturated hydrocarbons.

Complete answer:
Aromatic hydrocarbons are the hydrocarbons that are present in the form of rings of carbon atoms with alternative double bonds. But every conjugated hydrocarbon ring or every unsaturated organic compound is not an aromatic hydrocarbon. Thus there are a certain set of rules that must be followed in order to be called an aromatic hydrocarbon and these rules are called Huckel’s rules.
 Huckel's rule can be stated as follows:
The hydrocarbon must be planar in nature
The compound must contain $$4n+2$$ number of $$\pi$$ electrons
The compound must have a cyclic conjugation, i.e. a cyclic continuous delocalization of $$\pi$$ electrons must be present inside the compound.
Based on the given rules many organic compounds can be classified as aromatic compounds. One popular example of aromatic hydrocarbon is benzene with three alternative $$\pi$$ bonds. It is a six membered carbon ring that has resonating structures due to which the $$\pi$$ bonds keep delocalizing throughout the ring.

Note:
Even though all carbon atoms are not connected through a double bond in an aromatic hydrocarbon, the resonance or conjugation makes all the carbon-carbon bonds partially double bonded in nature due to which all the bond lengths are equal and an unsubstituted aromatic hydrocarbon is equally vulnerable to an electrophilic attack.