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The value of Kf of water is 1.86Kkgmol1. If 1 kg of water is filled in your automobile radiation then how much gm of ethylene glycol will be added to decrease the freezing point of the solution to 2.8C.


Answer
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Hint: Freezing point:- The temperature at which liquid turns into a solid when cooled is called a freezing point of that particular matter.

Complete answer:
Depression in freezing point:- When we add a non-volatile solid, in the pure liquid, the freezing point of the liquid is lowered, as the vapour pressure of the liquid is lowered, due to the presence of non-volatile solute particles at the surface of the liquid.
It is given that,
Let WA be the mass of ethylene glycol needed to be added to the automobile radiation.
Mass of the solvent (water) = WA=1kg=1000g
Kf of water = 1.86Kkgmol1.
Freezing point of water, Tf=0C
Freezing point of solution = 2.8C
Mass of the solute, MB=62g/mol
Now, use the formula;
ΔTf=TfTs=1000×Kf×WB÷WA×MB

WB=(TfTs)×WA×MB÷1000×Kf
= {0(2.8)}×1000×62÷1000×1.86
= 280÷3
= 93.33g
Therefore, the mass of ethylene glycol added, WB=93.33g.

Additional Information:
Adding a solute to a solvent decreases the temperature at which the liquid solvent becomes a solid.
At the freezing point, the vapour pressure of both the solid and liquid form of a compound must be equal.
It is a colligative property.

Note: The possibility to make a mistake is that there is a difference between the freezing point and freezing point depression. Freezing point is the temperature at which liquid turns into a solid when cooled is called a freezing point of that particular matter while freezing point depression is the difference in the freezing points of the solution.


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