
The heating of phenyl-methyl ethers with HI produces:
A.Benzene
B.Ethyl chlorides
C.Iodobenzene
D.Phenol
Answer
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Hint:Ether are basically a compound where two alkyl or aryl or one alkyl and one aryl group is bonded with oxygen. It can be formed by the dehydration of alcohols by emitting water molecules using dehydrating agents like Conc. .
Complete answer:
When ethers heated in presence of HI it dissociates into alcohol and alkyl iodide.
In presence of acid ether can be dissociated. For example, the presence of HI, it dissociates by the following mechanism.
This mechanism is the mechanism. The formation of alkyl iodide and alcohol depends upon the group attached to the oxygen. Between the secondary and Primary alkyl group, the primary alkyl group favors the attack at the iodide nucleophile to form corresponding alkyl iodide. Between secondary and tertiary alkyl groups, the secondary alkyl group favors the attack at the iodide nucleophile to form corresponding alkyl iodide. And between tertiary and Primary alkyl groups, the primary alkyl group favors the attack at the iodide nucleophile to form corresponding alkyl iodides. In between vinyl or benzyl group and alkyl group, alkyl group favors the attack at the iodide nucleophile to form corresponding alkyl iodide. Because vinyl and benzyl groups do not participate in the reaction.
Now for the phenyl methyl ether in presence of HI it will dissociates in the following manner,
Therefore, on heating of phenyl methyl ether in presence of HI, phenol is formed.
So, the correct answer is D.
Note:
Dissociation of ether undergoes in the mechanism. Always less bulky group will form corresponding alkyl iodide.
is a single step reaction in which inversion of configuration takes place while is a two step reaction, in first step formation of carbocation takes place and then the nucleophile attacks. In no inversion of configuration occurs.
Complete answer:
When ethers heated in presence of HI it dissociates into alcohol and alkyl iodide.
In presence of acid ether can be dissociated. For example, the presence of HI, it dissociates by the following mechanism.

This mechanism is the
Now for the phenyl methyl ether in presence of HI it will dissociates in the following manner,

Therefore, on heating of phenyl methyl ether in presence of HI, phenol is formed.
So, the correct answer is D.
Note:
Dissociation of ether undergoes in the
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