
What is the major product in the following reaction?
Answer
490.8k+ views
Hint: Elimination reactions is a very vast area of organic reactions. Elimination reactions involve removal of pairs of atoms or groups of atoms usually through action of bases, acids etc. It leads to transformation of organic compounds containing single carbon-carbon bonds to double or triple carbon-carbon bonds.
Complete answer:
These elimination reactions are majorly classified into ${E_1}$ (unimolecular elimination) and ${E_2}$ (bimolecular elimination).
${E_2}$ mechanism is a one step mechanism. In alkyl halides the carbon-halogen and carbon-hydrogen bond breaks in a single step forming a double bond. It is a second order reaction in which the rate depends upon both substrate and eliminating agent. The base usually abstracts the proton from the substrate and the leaving group (halogen mostly) leaves forming double bonded organic compounds. The important point to note is that the leaving group and the $\beta - H$ (that the base abstracts) should be antiperiplanar to each other.
The most common mechanism for dehydrohalogenation is the ${E_2}$ mechanism.
Now, coming to our question;
The given reaction is a dehydrohalogenation. It undergoes elimination via ${E_2}$ mechanism. Where bromide $\left( {Br} \right)$ is a leaving group and the base present $\left( {NaOMe} \right)$ will abstract the $\beta - H$ forming $3,3 - Dimethylcyclohexene$ .
We can clearly see that the leaving group bromide and the $\beta - H$ are antiperiplanar. Thus, the reaction takes place via the ${E_2}$ mechanism.
Note:
We should know about the ${E_1}$ mechanism as well. It takes place via two steps. There is a formation of carbocation as an intermediate in the ${E_1}$ mechanism. The reaction rate is proportional to only the concentration of substrate. It exhibits first-order kinetics. ${E_1}$ mechanism shows similar features as the $S{N_1}$ reaction.
Complete answer:
These elimination reactions are majorly classified into ${E_1}$ (unimolecular elimination) and ${E_2}$ (bimolecular elimination).
${E_2}$ mechanism is a one step mechanism. In alkyl halides the carbon-halogen and carbon-hydrogen bond breaks in a single step forming a double bond. It is a second order reaction in which the rate depends upon both substrate and eliminating agent. The base usually abstracts the proton from the substrate and the leaving group (halogen mostly) leaves forming double bonded organic compounds. The important point to note is that the leaving group and the $\beta - H$ (that the base abstracts) should be antiperiplanar to each other.
The most common mechanism for dehydrohalogenation is the ${E_2}$ mechanism.
Now, coming to our question;
The given reaction is a dehydrohalogenation. It undergoes elimination via ${E_2}$ mechanism. Where bromide $\left( {Br} \right)$ is a leaving group and the base present $\left( {NaOMe} \right)$ will abstract the $\beta - H$ forming $3,3 - Dimethylcyclohexene$ .
We can clearly see that the leaving group bromide and the $\beta - H$ are antiperiplanar. Thus, the reaction takes place via the ${E_2}$ mechanism.
Note:
We should know about the ${E_1}$ mechanism as well. It takes place via two steps. There is a formation of carbocation as an intermediate in the ${E_1}$ mechanism. The reaction rate is proportional to only the concentration of substrate. It exhibits first-order kinetics. ${E_1}$ mechanism shows similar features as the $S{N_1}$ reaction.
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