Question

Intermolecular H-Bonding is observed in how many of the following?

Answer 1

Hint:Intermolecular bonds are formed by the attraction between the negative part of one molecule and the positive part of another molecule. The intermolecular bond is stronger than the intramolecular bond.

Complete step by step answer:
The intermolecular bond takes place between two molecules, one containing hydrogen and the other containing electronegative atoms such as oxygen, nitrogen, or fluorine. Here, the compound catechol has two hydroxyl groups, they are attached at ortho position; hence, they undergo intramolecular force of attraction (bonding within a molecule), and similarly with resorcinol the presence of two hydroxyl groups at meta position, it undergoes bonding between a hydrogen atom and the oxygen atom of the same molecule, thereby undergoing intramolecular bonding. Whereas, the para hydroxy phenol undergoes intermolecular bonding, as they cannot undergo an intramolecular bond. The presence of the hydroxyl group at the para position undergoes intermolecular bonding with the other molecule. The compound 1,2 difluoro benzene undergoes intermolecular force of bonding since there is no interaction or presence of hydrogen within the compound to undergo intramolecular bonding; hence, the fluorine molecule undergoes intermolecular hydrogen bonding with another molecule. The 2-fluoro benzoic acid undergoes intramolecular bonding. The hydrogen of the carboxylic group undergoes bonding with the fluorine in the second position.
 Thus, para hydroxy phenol and 1,2 difluoro benzene undergo intermolecular bonding.

Note:
Hydrogen bonding is said to be a secondary type of bonding, it is a weaker bond. The hydrogen bonding is synonymous with Van Der Waals force of attraction. The hydrogen bond is responsible for the existence of solids of many organic molecules containing hydroxyl groups such as glucose and sucrose.