Courses
Courses for Kids
Free study material
Offline Centres
More
Store Icon
Store
seo-qna
SearchIcon
banner

For the strong electrolytes NaOH,NaCl and BaCl2, the molar ionic conductances at infinite dilution are 248×104,126.5×104 and 280.0×104s.m2.mol1 respectively. Calculate Λm for Ba(OH)2.

Answer
VerifiedVerified
483.6k+ views
like imagedislike image
Hint:Electrolytes are the substances whose solution in water conducts electric current. Conduction takes place by the movement of ions. Kohlrausch’s law is based on the limiting molar conductivity of an electrolyte.

Complete step by step answer:
Molar conductivity is the conductive power of all the ions produced by one mole of an electrolyte in the given solution. Kohlrausch’s law gives the empirical relationship between molar conductivity and concentration of strong electrolytes. Limiting molar conductivity is due to the migration of cations in one direction and anions in the other under very dilute conditions. The Kohlrausch’s law is expressed in the formula given below:
Λm=υ+Λ++υΛ, where Λ+,Λ are the ionic conductances of the cations and anions at infinite dilution.
It is given that molar ionic conductance of NaOH, Λm(NaOH)=248×104s.m2.mol1
Molar ionic conductance of NaCl, Λm(NaCl)=126.5×104s.m2.mol1
Molar ionic conductance of BaCl2, Λm(BaCl2)=280.0×104s.m2.mol1
Molar ionic conductance of NaOH can be expressed as Λm(NaOH)=Λm(Na+)+Λm(OH)
Molar ionic conductance of NaCl can be expressed as Λm(NaCl)=Λm(Na+)+Λm(Cl)
Molar ionic conductance of BaCl2 can be expressed as Λm(BaCl2)=Λm(Ba2+)+2Λm(Cl)
The reaction with respect to the formation of Ba(OH)2 is given below:
BaCl2+2NaOHBa(OH)2+2NaCl
Thus molar ionic conductance of Ba(OH)2 can be expressed as:
Λm[Ba(OH)2]=Λm(BaCl2)+2Λm(NaOH)2Λm(NaCl)
Λm[Ba(OH)2]=[Λm(Ba+)+2Λm(Cl)]+[2Λm(Na+)+2Λm(OH)][2Λm(Na+)+2Λm(Cl)]
On simplification, we get
Λm[Ba(OH)2]=[Λm(Ba+)]+[2Λm(OH)]
Substituting the values, we get
Λm[Ba(OH)2]=280.0×104s.m2.mol1+2×248×104s.m2.mol1(2×126.5s.m2.mol1)
Solving,
Λm[Ba(OH)2]=776.0×104s.m2.mol1253.0×104s.m2.mol1=523×104s.m2.mol1
Molar conductance of Ba(OH)2, Λm[Ba(OH)2]=523×104s.m2.mol1

Note: Specific conductance is the ability of an electrolyte solution to conduct electricity. On dilution, the specific conductivity decreases. Equivalent and molar conductance increase with dilution and reaches a maximum value. The conductance of all electrolytes increases with temperature. Kohlrausch’s law can be applied for calculating the degree of dissociation of a weak electrolyte. It can also be used for finding the equivalent conductivity of weak electrolytes.
Latest Vedantu courses for you
Grade 11 Science PCM | CBSE | SCHOOL | English
CBSE (2025-26)
calendar iconAcademic year 2025-26
language iconENGLISH
book iconUnlimited access till final school exam
tick
School Full course for CBSE students
PhysicsPhysics
ChemistryChemistry
MathsMaths
₹41,848 per year
Select and buy