Courses
Courses for Kids
Free study material
Offline Centres
More
Store Icon
Store
seo-qna
SearchIcon
banner

Among, KO2, AlO2, BaO2 and NO2+ unpaired electron is present in ___________.
A. NO2+ and BaO2
B. KO2 and AlO2
C. KO2 only
D. BaO2 only

Answer
VerifiedVerified
511.2k+ views
like imagedislike image
Hint: Find the total number of valence electrons in the molecules and then write configuration of these molecules. If the electrons are not coupled, the electrons are said to be unpaired. The configuration will be written according to molecular orbital theory.

Complete step by step answer:
(1) KO2: Potassium has its configuration as 2,8,8,1. The valence electron is 1. Oxygen has its configuration as 2,6. The valence electrons will be 6. The total valence electrons are 6+6+1 are 13 electrons. The configuration of will be σ1s2σ1s2σ2s2σ2s2π2px2π2py2π2px1. The π2px orbital has one unpaired electron.

(2) BaO2: Barium has its configuration as [Xe]6s2. The valence electrons are 2. Oxygen has its configuration as 2,6. The valence electrons will be 6. The total valence electrons are 6+6+2 are 14 electrons. The configuration of will be σ1s2σ1s2σ2s2σ2s2π2px2π2py2π2px2. All the orbitals are completely filled with electrons.

(3) AlO2 : Aluminium has its configuration as 2,8,3. The valence electrons are 3. Oxygen has its configuration as 2,6. The valence electrons will be 6. The total valence electrons are 6+6+3+1 are 16 electrons. The configuration of will be σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2π2py2π2px2. All the orbitals are completely filled with electrons.

(4) NO2+ : Nitrogen has its configuration as 2,5. The valence electrons are 5. Oxygen has its configuration as 2,6. The valence electrons will be 6. The total valence electrons are 5+6+6-1 are 16 electrons. The configuration of will be σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2π2py2π2px2. All the orbitals are completely filled with electrons.
The correct answer of this question is option ‘c’. Among, KO2, AlO2, BaO2 and NO2+ unpaired electron is present in KO2.
So, the correct answer is “Option C”.

Note: The electronic configuration for elements having electrons greater than 14 electrons is different with the configuration of elements having electrons less than equal to 14. Let us see the electronic configuration:
(1) Greater than 14 electrons: σ1sσ1sσ2sσ2sσ2pzπ2pxπ2pyπ2pxπ2py
(2) Electrons less than equal to 14 electrons: σ1sσ1sσ2sσ2sπ2pxπ2pyπ2pxσ2pzπ2pyσ2pz