
Ammonium silver nitrate solution is called:
A.reagent
B.Fehling solution
C.(A) and (B)
D.None of these
Answer
514.8k+ views
Hint: The alkaline solution of ammonium silver nitrate reacts with aldehydes to form carboxylic acid and metallic silver is formed which shines like a silver mirror. When it is reacted with ketones they do not react with it. Hence, Ammonium silver nitrate solution is used to distinguish between aldehydes and ketones.
Complete step by step answer:
Ammonium silver nitrate is a solution of silver nitrate and ammonia. It was named Tollen’s reagent after a German scientist Bernhard Tollens. It is used to test the aldehyde functional group .It has a short shelf- life hence it has to be prepared fresh for use. Its preparation is as follows-
In solution of silver nitrate, a few drops of sodium hydroxide is added and brown precipitate of silver oxide is obtained. The reaction is as follows-
This brown ppt. is then dissolved in ammonia to obtain complex.This complex is known as Tollen;s reagent.
When tollens reagent reacts with aldehyde, aldehyde is oxidized and forms carboxylic acid. The silver ions in tollen’s reagent convert to metallic silver which forms a silver mirror at the bottom of the test tube.This test is also known as silver mirror test.The reaction is –
Hence the correct option is A.
Additional Information:
- Fehling solution is prepared by mixing cupric sulphate penta-hydrate solution and Rochelle salt (potassium sodium tartrate tetra-hydrate).
-It is also used to distinguish between aldehydes and ketones because aldehydes give positive results to the test.
-It is also used to determine monosaccharide and other reducing sugars.
-It is also used to detect glucose in urine for diabetic patients.
-It is used in breakdown of starch to glucose syrup and maltodextrins. Maltodextrins are polysaccharides used as food additives.
Note:
The uses of ammonium silver nitrate solution are-
-It is used to distinguish between aldehydes and ketones.
-It is used to apply a silver mirror to clean glassware.
Complete step by step answer:
Ammonium silver nitrate is a solution of silver nitrate and ammonia. It was named Tollen’s reagent after a German scientist Bernhard Tollens. It is used to test the aldehyde functional group .It has a short shelf- life hence it has to be prepared fresh for use. Its preparation is as follows-
In solution of silver nitrate, a few drops of sodium hydroxide is added and brown precipitate of silver oxide is obtained. The reaction is as follows-
This brown ppt. is then dissolved in ammonia to obtain
When tollens reagent reacts with aldehyde, aldehyde is oxidized and forms carboxylic acid. The silver ions in tollen’s reagent convert to metallic silver which forms a silver mirror at the bottom of the test tube.This test is also known as silver mirror test.The reaction is –
Hence the correct option is A.
Additional Information:
- Fehling solution is prepared by mixing cupric sulphate penta-hydrate solution and Rochelle salt (potassium sodium tartrate tetra-hydrate).
-It is also used to distinguish between aldehydes and ketones because aldehydes give positive results to the test.
-It is also used to determine monosaccharide and other reducing sugars.
-It is also used to detect glucose in urine for diabetic patients.
-It is used in breakdown of starch to glucose syrup and maltodextrins. Maltodextrins are polysaccharides used as food additives.
Note:
The uses of ammonium silver nitrate solution are-
-It is used to distinguish between aldehydes and ketones.
-It is used to apply a silver mirror to clean glassware.
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